Gianluca, My measurements of the coordinates of RZ Leo during quiescence can be found in the Sumner sequence at: http://ftp.nofs.navy.mil/pub/outgoing/aah/sequence/sumner/rzleo.dat and are: 11 37 22.27 +01 48 58.7 J2000 which are in agreement with your measures of 11 37 22.27 +01 48 58.9 The master CV catalog of Downes, Webbink and Shara (PASP 109, 345, 1997, often referred to as DWS in this business) give 11 37 22.30 +01 48 57.8 again in agreement with the two measures above, considering that they were using the GSC for their astrometric reference. The discrepancy with Simbad is that Simbad is using the coordinates from the first CV catalog (Downes and Shara, PASP 105, 127, 1993, also known as D&S). There was a misidentification in that earlier catalog. This is a common problem with CVs that did not have good astrometry when they were discovered in outburst and which have not been seen in outburst since. Downes and Shara have done the best job they could, but you will find many such misidentifications on the poorly observed cataclysmics. The way I've found many of these is by color; deep exposures are necessary to find CV's at 20th magnitude in B&V, but it can be done. Such a technique is not perfect, as many CVs are very red in quiescence, but it picks out the blue ones pretty easily. However, you should report this coordinate discrepancy to Simbad to update their database. Arne